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6PPD (4020) CAS 793-24-8

793-24-8 –Names and Identifiers

Name N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamine
Synonyms BHTOX-4020
Flexzone 7F
Vulkanox 4020
Santoflex6PPD
Antoxidant 6ppd
Antoxidant 4020
Santoflex 134PD
Antioxidant 4020
N-(1,3-Dimethylbutyl
Rubber Antioxidant 4020
SANTOFLEX(R) 13 PASTILLES
Rubber Antioxidant 4020PPD
N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamine
N-(1,3-Dimethylbutyl)-N-Phenyl-1,4-Benzenediamine
N-(1,3-Dimethylbutyl)-N-Phenyl-p-phenylene Diamine
N-(1,3-Dimethylbutyl)-N’-phenyl-p-phenylenediamine
N-(1.3-dimethylbutyl)-N’-phenyl-p-phenylenediamine
N-(4-methylpentan-2-yl)-N’-phenylbenzene-1,4-diamine
1,4-BenzenediaMine,N1-(1,3-diMethylbutyl)-N4-phenyl-
N1-(4-methylpentan-2-yl)-N4-phenyl-benzene-1,4-diamine
1-N-(4-methylpentan-2-yl)-4-N-phenylbenzene-1,4-diamine
4020,N-(1,3-DiMethylbutyl)-N’-phenyl-p-phenylenediaMine
CAS 793-24-8
EINECS 212-344-0
InChI InChI=1/C18H24N2/c/h4-12,14-15,19-20H,13H2,1-3H3
InChIKey ZZMVLMVFYMGSMY-UHFFFAOYSA-N

793-24-8 –Physico-chemical Properties

Molecular Formula C18H24N2
Molar Mass 268.4
Density 0.986~1.00g/cm3
Melting Point 45-46°C
Boling Point 260°C
Flash Point 204°C
Water Solubility <0.1 g/100 mL at 17 ºC
Solubility soluble in Methanol
Vapor Presure 5.22E-07mmHg at 25°C
Appearance Dark brown black solid
Color Light orange to Dark red to Black
pKa 6.73±0.32(Predicted)
Storage Condition Keep in dark place,Sealed in dry,Room Temperature
Refractive Index 1.6300 (estimate)
MDL MFCD00072248
Physical and Chemical Properties Gray-black solid.
Use Natural rubber and synthetic rubber with anti-ozone agent and antioxidant, ozone crack and flex fatigue excellent protective effect

793-24-8 –Risk and Safety

Risk Codes R22 – Harmful if swallowed
R43 – May cause sensitization by skin contact
R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Description S36/37 – Wear suitable protective clothing and gloves.
S60 – This material and its container must be disposed of as hazardous waste.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
UN IDs UN 3077 9 / PGIII
WGK Germany 2
RTECS ST0900000
HS Code 29215190
Hazard Class 9
Packing Group III
Toxicity LD50 oral in rat: 3580mg/kg

793-24-8 –Reference Information

purpose the product is a polluting antioxidant, in addition to good Antioxidant efficacy, and anti-ozone, anti-bending to find the role of cracking and inhibition of copper, manganese and other harmful metals. Its performance is similar to that of antioxidant 4010NA, but its toxicity and skin irritation are smaller than 4010NA, and its solubility in water is better than 4010NA (water loss rate: 4010NA is 50%, and 4020 only 15-20%). Can be widely used in the preparation of tires, tape and many other industrial rubber products, the general dosage of 0.5-1.5%. This product is not suitable for making light-colored products due to serious pollution. Antioxidant 4020 is one of the main varieties of p-phenylenediamine antioxidant. P-phenylenediamine antioxidant is the main good varieties commonly used in rubber industry at home and abroad, and it is also the development direction of antioxidant in the future.
It is an antiozonant and antioxidant for natural rubber and synthetic rubber, and has excellent protective effect against ozone cracking and flex fatigue
production method a variety of methods can be used to prepare antioxidant 4020. Generally, 4-aminodiphenylamine is obtained by catalytic hydrocondensation with methyl isobutyl ketone. N-(1, 3-dimethylbutyl)-p-aminophenol can also be used to react with aniline at 210-230 °c under the catalysis of iron powder and iodine (or FeCI2, FeCI3), after the condensation reaction is completed, the mixture of the product is obtained by distilling off the volatile substances at 180 ° C. (133 Pa), which is divided into: N-(1, 3-dimethylbutyl)-N’-phenyl-p-phenylenediamine 50%,N,N’-diphenyl-p-phenylenediamine 17.5%,N,N’-bis (1, 3-dimethylbutyl)-p-phenylenediamine 13.4%.

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