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4-ADPA 4-Aminodiphenylamine CAS 101-54-2

101-54-2 –Names and Identifiers

Name 4-Amino diphenylamine
Synonyms azosaltr
Azosalt R
C.I. 76085
C.I. 37240
blackbasep
Luxan Black R
fastbluersalt
FastblueRTbase
acnablackdfbase
Fast Blue R Salt
C.I. Developer 15
VARIAMINE BLUE RT
Acna Black DF Base
4-amino-diphenylamin
p-Aminodiphenylamine
4-Aminodiphenylamine
C.I. Oxidation Base 2
4-Amino diphenylamine
4-(Phenylamino)aniline
Variamine Blue RT Base
Benzenediamine, N-phenyl-
N-phenylbenzene-1,4-diamine
N-Phenyl-P-Phenylenediamine
4-Benzenediamine,N-phenyl-1
C.I. Azoic Diazo Component 22
N-Phenyl-1,41phenylenediamine
CAS 101-54-2
EINECS 202-951-9
InChI InChI=1/C12H12N2/c/h1-10H,13H2

101-54-2 –Physico-chemical Properties

Molecular Formula C12H12N2
Molar Mass 184.24
Density 1.09
Melting Point 69 °C
Boling Point 354 °C
Flash Point 193°C
Water Solubility Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol.
Solubility ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution)
Vapor Presure 1 hPa
Appearance Form Liquid, color Clear
Color Clear
BRN 908935
pKa 5.20±0.10(Predicted)
PH 8.9 (0.5g/l, H2O, 20℃)
Storage Condition Store below +30°C.
Stability Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics.
Refractive Index 1.6266 (estimate)
Physical and Chemical Properties Gray needle crystal.
melting point 72 ℃
boiling point 354 ℃
solubility soluble in organic solvents such as ethanol, ether, can also be soluble in acid, alkali solution, slightly soluble in water.
Use Intermediates for dyes and auxiliaries

101-54-2 –Risk and Safety

Risk Codes R22 – Harmful if swallowed
R36 – Irritating to the eyes
R43 – May cause sensitization by skin contact
R42/43 – May cause sensitization by inhalation and skin contact.
R36/37/38 – Irritating to eyes, respiratory system and skin.
R20/22 – Harmful by inhalation and if swallowed.
R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Description S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 – Wear suitable protective clothing.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S61 – Avoid release to the environment. Refer to special instructions / safety data sheets.
S60 – This material and its container must be disposed of as hazardous waste.
S36/37 – Wear suitable protective clothing and gloves.
UN IDs UN3077
WGK Germany 3
RTECS ST3150000
FLUKA BRAND F CODES 8
TSCA Yes
HS Code 29215990
Hazard Note Irritant
Hazard Class 9
Packing Group III
Toxicity LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg

101-54-2 –Upstream Downstream Industry

Raw Materials 1-Chloro-4-nitrobenzene
Aniline
1-Chloro-4-nitrobenzene
Formic acid
Sodium sulfide
Hydrogen
Potassium carbonate
Nitrobenzene
Downstream Products N-isopropyl-N’-phenyl-p-phenylenediamine
N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamine

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