4-ADPA 4-Aminodiphenylamine CAS 101-54-2
101-54-2 –Names and Identifiers
| Name | 4-Amino diphenylamine |
| Synonyms | azosaltr Azosalt R C.I. 76085 C.I. 37240 blackbasep Luxan Black R fastbluersalt FastblueRTbase acnablackdfbase Fast Blue R Salt C.I. Developer 15 VARIAMINE BLUE RT Acna Black DF Base 4-amino-diphenylamin p-Aminodiphenylamine 4-Aminodiphenylamine C.I. Oxidation Base 2 4-Amino diphenylamine 4-(Phenylamino)aniline Variamine Blue RT Base Benzenediamine, N-phenyl- N-phenylbenzene-1,4-diamine N-Phenyl-P-Phenylenediamine 4-Benzenediamine,N-phenyl-1 C.I. Azoic Diazo Component 22 N-Phenyl-1,41phenylenediamine |
| CAS | 101-54-2 |
| EINECS | 202-951-9 |
| InChI | InChI=1/C12H12N2/c/h1-10H,13H2 |
101-54-2 –Physico-chemical Properties
| Molecular Formula | C12H12N2 |
| Molar Mass | 184.24 |
| Density | 1.09 |
| Melting Point | 69 °C |
| Boling Point | 354 °C |
| Flash Point | 193°C |
| Water Solubility | Soluble in water at 20°C 0.6g/L. Soluble in (10 mg/mL) ethanol. |
| Solubility | ethanol: soluble10mg/mL, clear, very dark red (Violet to brown to black solution) |
| Vapor Presure | 1 hPa |
| Appearance | Form Liquid, color Clear |
| Color | Clear |
| BRN | 908935 |
| pKa | 5.20±0.10(Predicted) |
| PH | 8.9 (0.5g/l, H2O, 20℃) |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, plastics. |
| Refractive Index | 1.6266 (estimate) |
| Physical and Chemical Properties | Gray needle crystal. melting point 72 ℃ boiling point 354 ℃ solubility soluble in organic solvents such as ethanol, ether, can also be soluble in acid, alkali solution, slightly soluble in water. |
| Use | Intermediates for dyes and auxiliaries |
101-54-2 –Risk and Safety
| Risk Codes | R22 – Harmful if swallowed R36 – Irritating to the eyes R43 – May cause sensitization by skin contact R42/43 – May cause sensitization by inhalation and skin contact. R36/37/38 – Irritating to eyes, respiratory system and skin. R20/22 – Harmful by inhalation and if swallowed. R50/53 – Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
| Safety Description | S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 – Wear suitable protective clothing. S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection. S61 – Avoid release to the environment. Refer to special instructions / safety data sheets. S60 – This material and its container must be disposed of as hazardous waste. S36/37 – Wear suitable protective clothing and gloves. |
| UN IDs | UN3077 |
| WGK Germany | 3 |
| RTECS | ST3150000 |
| FLUKA BRAND F CODES | 8 |
| TSCA | Yes |
| HS Code | 29215990 |
| Hazard Note | Irritant |
| Hazard Class | 9 |
| Packing Group | III |
| Toxicity | LD50 orally in Rabbit: 464 mg/kg LD50 dermal Rabbit > 5000 mg/kg |
101-54-2 –Upstream Downstream Industry
| Raw Materials | 1-Chloro-4-nitrobenzene Aniline 1-Chloro-4-nitrobenzene Formic acid Sodium sulfide Hydrogen Potassium carbonate Nitrobenzene |
| Downstream Products | N-isopropyl-N’-phenyl-p-phenylenediamine N-1,3-dimethylbutyl-N’-phenyl-p-phenylenediamine |
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