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Butylated Urea Formaldehyde Resin

Introduction

Butylated Urea-Formaldehyde Resin(BUF) is a modified product of urea-formaldehyde resin (synthesized by the polycondensation of urea and formaldehyde) throughbutanol etherification. By reacting butanol with the hydroxymethyl groups (-CH2OH) in urea-formaldehyde resin, butoxy-substituted derivatives are formed, enhancing its properties:

Solubility: Improved solubility in organic solvents (e.g., xylene, alcohols), making it suitable for solvent-based coating systems.

Stability: Reduced tendency for hydroxymethyl self-condensation, enhancing storage stability.

Flexibility: Lower brittleness, improving impact resistance of coatings or adhesive layers.

Compatibility: Better miscibility with other resins (e.g., alkyd resins, epoxy resins).

Key Applications

Coatings Industry

Cross-linking Agent: As a type of amino resin, it is combined with alkyd resins, acrylic resins, etc., in high-temperature curing coatings (e.g., automotive topcoats, coil coatings, industrial baking paints) to provide high gloss, hardness, and chemical resistance.

Wood Coatings: Used in furniture and floor paints to enhance surface wear and scratch resistance.

Adhesives

Wood Bonding: Applied in particleboard and plywood production, offering improved water resistance compared to conventional urea-formaldehyde resins.

Laminated Materials: Provides strong adhesion in composites with paper or fabrics.

Composite Materials

Molding Compounds: Serves as a matrix resin for electrical components and automotive parts, enhancing heat resistance and dimensional stability.

Other Fields

Inks: Used as a binder to improve weather resistance and adhesion of printed materials.

Textile Auxiliaries: Acts as a fabric finishing agent to enhance wrinkle resistance and hand feel.

Advantages and Limitations

Advantages: Low cost, fast curing, high hardness, and solvent resistance.

Limitations: May release trace formaldehyde; less environmentally friendly compared to water-based or formaldehyde-free resins (e.g., polyurethane, acrylic).

Fundamental Chemical Properties

PropertySpecification
Chemical Name Butylated Urea Formaldehyde Resin
CAS Number [Not specified]
Molecular Structure Modified UF resin with butanol etherification
Appearance Colorless to pale yellow viscous liquid
Solid Content 50-60%
Viscosity (25°C) 200-800 mPa·s
pH Value 7.5-9.0
Solubility Water-miscible

Key Performance Characteristics

ParameterTest MethodTypical Value
Cure Temperature DSC 100-130°C
Gel Time (120°C) ISO 8985 90-180 sec
Flexural Strength ASTM D790 80-110 MPa
Water Resistance 24h immersion ≤2% weight gain
Storage Stability 25°C/6 months ≤10% viscosity change

Application Guidelines

ApplicationTechnical Parameters
Wood Adhesives Press time: 60-90 sec at 110°C
Coatings 10-15% resin solids content
Paper Impregnation 40-50% pickup rate
Curing System Acid catalyst required (pH 3-5)
Pot Life 4-8 hours (after catalyst addition)

Key Features:

Enhanced water resistancevs conventional UF resins

Lower formaldehyde emission(<0.1 ppm by chamber test)

Improved flexibilitywith butoxylation modification

Excellent adhesionto cellulose materials

Thermosettingwith irreversible cure


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